I find that depending on the flow rate, (ie, the general speed of the water.) and general light is how I adjust my shutter speed and F stop. I usually shoot it at ISO 100 and use a graduated ND filter to get from 1/3 to 1 second exposure. Otherwise the water just looks like a blob of white. I like to be able to tell that it's water. F8, being the optimum stop for most landscape shots, is usually a good start too.