On the D750 the ISO lower than 100 has no direct impact on quality but it can be used when you prefer one stop of (incoming) light more for the same scene or to use a specific aperture 100 does not allow (lowering to 50 forces you to adjust A or S) or to handle a very bright scene where your shutter might otherwise be limited by its maximum speed. I like it when shooting against the sun since I hit my shutter limit frequently then.
I use it mainly to increase my total amount of exposure to light for a shot but about only when shooting landscapes on a tripod. In doing so it indirectly impacts quality but in terms of technical quality, like the cam's DR or color sensitivity and sharpness, all below 100 is identical to ISO 100, at least for the D750. The reason I use it has nothing to do with the cam but all with the fluctuation of light.
Higher than 12800 probably has a use in very limited scenarios but the shots I took to test it were very, very noisy.